How to mordant linen and cotton fabrics successfully

I have received a lot of emails the last couple of weeks, asking about  how to mordant linen and cotton fabric. After repeatedly answering the same question over and over again, I thought why not post it on the blog?

There are several different methods of mordanting cellulose fibres, but I found the following technique the most practical. Many other recipes require Alum acetate, which I personally avoid using. I like to use what I have at hand and this recipe works a treat. Keep in mind that you will need time. This can be done within 4-5 hours or over a couple of days. 

You can find a tip section at the end of this article - a shorter version of the text below.

There are several different tannin rich plants that can be used, each slightly different from the next. Tannin will always leave some colour behind. Tara is the lightest tannin with a light beige, followed by Oak Gall. Myrobalan, pomegranate are leaving yellow backgrounds. Another little trick - if you add your fabric to a 2-5% iron after bath, your fabric will turn grey to dark grey/black/purple once it has been mordanted with a tannin rich dye. If that is the colour you require - leave out the Alum/Soda Ash Step. Alum brightens dyes, which might result in steely purple.

 

Before we start, if you want to dye your fabric with Indigo - no mordanting is required. You only need to scour your fabric. 

 

Indigo vat

A mineral Indigo Vat

Scouring

Scouring cotton                     scoured cotton

Before (left) and after (right) scouring single layered organic cotton

       Equipment

  • A pot big enough to hold your fabric
  • 1 tsp of Soda Ash (or 1% of w.o.f.( w.o.f. stands for weight of fibre))
  • 1/2 -1 tsp of organic washing up liquid
  • Heat resistant rubber gloves
Instructions:
Wet fabric thoroughly.
Dissolve the Soda Ash in a little hot water and add to the pot, followed by the washing up liquid.
Add the fabric to the pot and stir.
Bring pot to the boil and keep at a light simmer for an hour. Stirring regularly. 
Remove fabric, let cool and give it a good rinse.
NEXT:

Mordanting cellulose fabrics successfully.

 A 2 step process, please read through the entire instructions first.


Step 1:

Ingredients:

10-60% Tannin rich plant like Myrobalan (10% of the weight of fabric (w.o.f.)) other options would be Oak Gall, Sumac and Tara and any other source of tannin.

Myrobalan

1.Fill a plastic or stainless steel vessel with cold water (40degrees Celsius/104F max) to a 30:1 ratio (water:fabric)

2. Add tannin and stir until dissolved or evenly distributed, ( I use a blender) 

3. Add fabric, immerse fully for at least 1-2 hours up to 24h.  Stir occasionally.


4. Use rubber gloves when removing fabric, squeeze fabric. Let it drip. Do not rinse! Tannin is bound to the fibre only by affinity and can be removed if rinsed aggressively.

5. Save mordant for future use.

6. Don't let it dry before moving on to Step 2.

Step 2:

Ingredients:
Alum 12% (w.o.f.) Dissolved in enough hot water.
Soda Ash 1.5% (w.o.f.) Dissolve in enough hot water.

1. Combine the two solutions while stirring. It might bubble, so make sure your vessel is big enough.

2. Bubbles will subside quickly, if any, and you should be left with a cloudy liquid. Add additional cold water if needed.

3. Leave for a minimum of 2h up to 24h.

4. Rinse the textile well, to make sure any unattached mordant is rinsed off.

5. Mordant bath can be re-used.

6. The textile may be dyed immediately or dried for future use.

Tips:

*Too hot and the tannin will oxidize, which is fine, if you want a potentially darker colour. For overdyeing, it is best to keep the colour as light as possible though.
**Any tannin can be used with this recipe, but for lighter results use Oak Gall or Tara or Sumac leaves.

 

Answers to Comments ( I don't seem to be able to answer directly unfortunately), but you can always message me :)

What is w.o.f.? Short for 'weight of fabric or fibre'

Can I use Sumac leaves instead? Yes, dry or fresh, both work :)

I have noticed however that the soda ash remains cloudy even though I have dissolved it in boiling water, it eventually settles on the bottom. Is this unusual? Will it affect the overall colorfastness/ lightfastness of the dye? Soda Ash, when dissolving, can leave a clear out cloudy liquid behind. I think it might depends on water temperature. Stirring will eventually dissolve it, or or some liquid in the Morant put and use some more fresh hot water.


25 comments


  • Jennifer Lienhard

    Dear Zsuzsanna, you are very welcome, I am delighted it is of help :) Best wishes, Jennifer


  • Zsuzsanna Schenk

    Herzlichen Dank für Ihre Anleitung, die Sie mir gerade geschenkt haben! Diese Tipps werde ich befolgen. Sie haben es sehr informativ und sehr gut verständlich formuliert.


  • Jennifer Lienhard

    Hello Gail, thank you for your question! Soda Ash is used in scouring to open up the fibres by bringing the pH up. Once rinsed, we apply a tannin mordant. The tannins need to be turned into tannates in order to make them insoluble. That is done by combing Aum and Soda ash and adding the tannin soaked textile to it for a minimum of 2 hours. Only then can the textile be used for dyeing, as the tannin is now insoluble and cannot be washed away. I hope that explains it. Cream of tartar will discharge a mordant on cellulose fibres and is only used with a protein mordant when using a hot alum mordant application. I hope that answers your question :)


  • Gail

    It’s somewhat confusing when soda ash is used both for scouring and as a mordant. If one scours with soda ash & rinses well, then why the additional bath in soda ash, with or without Alum and/or cream of tartar?


  • Jennifer Lienhard

    Hiya! if you have done the scouring and mordanting on the textile once already, than there is no need to do it again :)


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